Product Name:

Thormaseal Tropical AP

Suppliers name:

Prismo Road Markings Limited (Trading as Ennis-Flint)

5 Drumhead Road,

Chorley North Industrial Estate,

Chorley, Lancashire,

PRO 7BX

United Kingdom

Telephone Number: +44 (0) 1257 225 100

Fax Number: +44 (0) 1257 224 606

Email Address: info@ennisflint.com

+44 (0) 1257 225 100

Only available office hours Monday – Friday 0830 to 1700 (English language)

Signal word: WARNING

Hazard Statements:

H317 May cause an allergic skin reaction.

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements:

P261                      Avoid breathing dust.

P280                      Wear protective gloves.

P302 + P352                       IF ON SKIN: Wash with plenty of water.

P333 + P313                       If skin irritation or rash occurs: Get medical advice/attention.

P362 + P364                       Take off contaminated clothing and wash it before reuse.

P501                                      Dispose of contents/container in accordance with local/national regulation

This mixture does not contain any substances that are assessed to be PBT or vPvB.

The product may give potential for generation of respirable dust during handling and use. Dust may contain respirable crystalline silica. Prolonged and or high inhalation of respirable crystalline silica dust may cause lung fibrosis, commonly referred to as silicosis. Principal symptoms of lung fibrosis are cough and breathlessness. Occupational exposure to respirable dust and respirable crystalline silica should be monitored and controlled.

3.2               Mixtures                                                     

                      3.3 Hazardous ingredients

The full hazard information for individual components if not displayed in Section 2 or 3 are displayed in Section 16.

                      General advice

Immediate medical attention is required if in contact with hot product. Move out of dangerous area. Show this safety data sheet to the doctor in attendance.

                      Inhalation

Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Get medical attention immediately. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.

Get medical attention if adverse health effects persist or are severe.

Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Wash skin immediately with soap and water. Get medical attention if irritation develops and persists.

If contact with hot product, cool the burn area by flushing with large amounts of water. Do not attempt to remove anything from the burn area or apply burn creams or ointments. Cover the burn area loosely with a sterile dressing, if available. Transport to the nearest medical facility for additional treatment. All burns should receive medical attention.

Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact

Cold product – Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Protect unharmed eye. Continue to rinse and get medical attention immediately. Continue to rinse during transport. If eye irritation persists, consult a specialist.

Hot product – If contact with hot product, cool the burn area by flushing with large amounts of water. Do not attempt to remove anything from the burn area or apply burn creams or ointments. Cover the burn area loosely with a sterile dressing, if available. Transport to the nearest medical facility for additional treatment. All burns should receive medical attention.

Over-exposure signs/symptoms

Inhalation

No specific information.

Ingestion

No specific information.

Skin

Contact with hot product may cause burns.

Product contains a skin sensitising substance. Prolonged or repeated exposure may cause skin sensitisation. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Adverse symptoms may include the following: irritation, redness.

Eyes

Contact with hot product may cause burns and severe damage to eyes. Product and dust may cause irritation to eyes.

See SECTION 11 for more detailed information on health effects and symptoms.

Notes to physician

No specific treatment. Treat symptomatically. If removal of solidified product from skin is attempted, mineral oil (not mineral spirits) or a mineral oil based ointment may be applied to help soften the product to facilitate removal.

Protection of first aid personnel

No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

                      Suitable

Use water spray, fog or foam, carbon dioxide. Use an extinguishing agent suitable for the surrounding fire

                      Not suitable Do not use water jet.

5.2                Special hazards arising from the substance or mixture

In a fire or if heated, a pressure increase may occur. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous thermal decomposition products In combustion may emit toxic fumes.

5.3                 Advice for firefighters

                      Special precautions for fire-fighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

                      Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in

positive pressure mode.

Avoid contact with skin, eyes and clothing. Hot product should be handled so that there is no risk of burns.  No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation.

Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Avoid breathing vapour or mist.

6.2                Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

6.3                Methods and material for containment and cleaning up

Small spill:

Eliminate all ignition sources. Move containers from spill area. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Large spill:

Eliminate all ignition sources. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Contaminated absorbent material may pose the same hazard as the spilled product.

6.4                 Reference to other sections

Note: see SECTION 1 for emergency contact information, SECTION 8 for personal protection and SECTION 13 for waste disposal

Avoid contact with skin, eyes and clothing. Avoid generation and breathing of dusts. Hot product should be handled so that there is no risk of burns.

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should

wash hands and face before eating, drinking and smoking. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used.

Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing dust, vapour or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

7.2                 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use.

Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

7.3                 Specific end use(s)

Supplied for use as a professional use surface dressing for application to road surfaces.

Workplace exposure Limits as defined by UK HSE in document EH40/2005 where available:

Fatty acids C18 unsat, reaction products with Pentaethylenehexamine: DNELs:

PNECs:

8.2                Exposure controls

General

Avoid contact with skin, eyes and clothing. Hot product should be handled so that there is no risk of burns.

                      Hygiene measures

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure that there is sufficient ventilation of the area.

 Eye and face protection Wear tightly fitting safety goggles and Face shield that meet EN 166 a/o ANSI Z87.1 standards

                      Skin Protection

When handling heated product wear heat resistant gloves.

Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact. Always seek advice from glove suppliers. Select gloves approved to EU standard EN407.

Wear impermeable protective clothing, butyl rubber apron and boots.

For normal operations with hot material wear heat resistant coveralls, (with cuffs over gloves and legs over boots), and heavy-duty boots, e.g. leather for heat resistance. The use of a neck apron is recommended.

                      Inhalation

Provide a good standard of general ventilation. Use outdoors or ensure not less than 3 to 5 air changes per hour. In case of dust wear respiratory protective device with dust filter. Applicable standards for continuous wear time of less than 2 hour are BS EN 140 mask and BS

EN 143 Filter; BS EN 1827.

9.2                 Other information

No other relevant information available

Stable under normal conditions.

10.2               Chemical stability

Stable under normal conditions.

10.3              Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4              Conditions to avoid

Avoid strong bases, acids and strong oxidising agents.

10.5              Incompatible materials

Do not allow molten material to contact water or liquids as this can cause violent eruptions, splatter hot material, or ignite flammable material.

10.6              Hazardous decomposition products

In combustion may emit toxic fumes.

The mixture has not been assessed for toxicological effects, the mixture classification is given in Section 2 based on individual component contents. Individual component hazards are given in Section 3

11.1.1            Acute toxicity

Not expected to be toxic.

                      Skin corrosion/irritation Product is not classified as causing skin irritation

                      Serious eye damage/irritation Product is not classified as causing severe eye irritation or eye damage.

                      Respiratory of skin sensitisation Product is classified as causing skin sensitisation.

                      Germ cell mutagenicity

No information specified.

                      Carcinogenicity No information specified.

                      Reproductive toxicity No information specified.

                      STOT-single exposure

Product is not classified as having Specific Target Organ Toxicity of single exposure.

                      STOT-repeated exposure

No information specified.

                      Aspiration hazard

No information specified.

                      Toxicological information on hazardous ingredients where available: Fatty acids C18 unsat, reaction products with Pentaethylenehexamine:

                      Inhalation

Inhalation of aerosols may cause irritation to mucous membranes. Thermal decomposition can lead to release of irritating gases and vapours. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

                      Skin

Symptoms may be delayed. May cause an allergic skin reaction. Causes severe skin burns.

                      Eyes Causes serious eye damage.

                      Further Information

No further information available.

Acute oral toxicity

LD50: > 2,000 – 5,000 mg/kg

Species: Rat

                      Skin corrosion/irritation

Result: Corrosive, category 1C – where responses occur after exposures between 1 hour and 4 hours and observations up to 14 days.

                      Sensitisation

Result: May case sensitisation by skin contact.

                      Source

AkzoNobel SDS 01.06.2015 Wetfix AP17 

Mixture not classified as harmful to aquatic life.

Toxicity of ingredients where available:

Fatty acids C18 unsat, reaction products with Pentaethylenehexamine:

Toxicity to fish                                                                                        LC50: > 0.01 – 0.1 mg/l

Exposure time: 96 h

Species: Fish

Read-across (analogy)

Toxicity to daphnia and other aquatic invertebrates                               NOEC: > 0.01 -0.1 mg/l

(Chronic toxicity)                                                                                     Exposure time: 21 d

Species: Daphnia magna (Water Flea)

Toxicity to algae                                                                                     ErC50: 0.01 – 0.1 mg/l

Exposure time: 72 h

Species Pseudokirchneriella subcapitata (green algae)

Method: OECD Test Guideline 201

                      M-Factor (Acute) 10

                      Source

AkzoNobel SDS 01.06.2015 Wetfix AP17

12.2              Persistence and degradability

Information not available

12.3               Bioaccumulative potential

No information

12.4               Mobility in soil

No information

12.5               Results of PBT and vPvB

This mixture does not contain any substances that are assessed to be PBT or vPvB

12.6               Other adverse effects

No information

                      Methods of disposal

The generation of waste should be avoided or minimized wherever possible.

Empty containers or liners may retain some product residues.

This material and its container must be disposed of in a safe way.

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

                      Hazardous waste

The classification of the product may meet the criteria for a hazardous waste.

Not applicable

14.2               UN proper shipping name

Not applicable

14.3              Transport hazard

Not applicable

14.4               Packing group

Not applicable

14.5              Environmental hazards

Product is not classified as harmful to the environment

14.6               Special precautions for user

No information available

14.7               Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code

Application for Maritime bulk transport only. Check with carrier.

This substance is classified and labelled in accordance with regulation 1272/2008 and Regulation (EC) No 1907/2006 of the European

Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2               Chemical Safety Assessment

CSA not undertaken for this substance

                      Reasons for Revision

Updated to reflect revised formulation of product: Sections 3, 8, 11, 12. Annex to the extended Safety Data Sheet (eSDS) removed.

Abbreviations

                      Other Hazard Information assigned to individual ingredients, but not carried to final classification H314: Causes severe skin burns and eye damage

H400: Very toxic to aquatic life

H410: Very toxic to aquatic life with long lasting effects

This safety data sheet is compiled using data submitted for raw materials and practical experience. This product is intended for professional users only.

This Safety Data Sheet is prepared in compliance with regulation 1272/2008 and Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

THE INFORMATION GIVEN HEREIN IS, TO THE BEST OF OUR KNOWLEDGE, CORRECT AND IS PRESENTED IN GOOD FAITH BUT NO WARRANTY, EXPRESSED OR IMPLIED IS GIVEN.