Epicol U B M.S.D.S
| 1 | SECTION 1: Identification of the substance/mixture and of the company/undertaking: |
1.1 Product identifier:
Epicol U B
1.2 Relevant identified uses of the substance or mixture and uses advised against:
For professional use only
Concentration in use: /
1.3 Details of the supplier of the safety data sheet:
RESIPLAST NV
Gulkenrodestraat 3
B2160 Wommelgem
Phone: 033200211 — Fax: 033226380
E-mail: info@resiplast.be — Website: http://www.resiplast.be/
1.4 Emergency telephone number:
+32 70 245 245
| 2 | SECTION 2: Hazards identification: |
2.1 Classification of the substance or mixture:
Classification of the substance or mixture in accordance with regulation (EU) 1272/2008:
H302 Acute tox. 4 H314 Skin Corr. 1B H317 Skin Sens. 1 H331 Acute tox. 3 H341 Muta. 2
2.2 Label elements:
Pictograms:
Signal word:
Danger
Hazard statements:
H302 Acute tox. 4: Harmful if swallowed.
H314 Skin Corr. 1B: Causes severe skin burns and eye damage.
H317 Skin Sens. 1: May cause an allergic skin reaction.
H331 Acute tox. 3: Toxic if inhaled.
H341 Muta. 2: Suspected of causing genetic defects.
Precautionary statements:
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
Contains:
m-phenylenebis(methylamine) Benzyl alcohol Diethylenetriamine
2.3 Other hazards:
none
| 3 | SECTION 3: Composition/information on ingredients: | |||||
| Benzyl alcohol | 5% – 15% | CAS number: | 100-51-6 | |||
| EINECS: | 202-859-9 | |||||
| REACH Registration number: | 01-2119492630-38 | |||||
| CLP Classification: | H302 Acute tox. 4
H319 Eye Irrit. 2 H332 Acute tox. 4 |
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| m-phenylenebis(methylamine) | 5% – 15% | CAS number: | 1477-55-0 | |||
| EINECS: | 216-032-5 | |||||
| REACH Registration number: | 01-2119480150-50 | |||||
| CLP Classification: | H302 Acute tox. 4
H314 Skin Corr. 1B H317 Skin Sens. 1 H332 Acute tox. 4 H412 Aquatic Chronic 3 |
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| Diethylenetriamine | 5% – 15% | CAS number: | 111-40-0 | |||
| EINECS: | 203-865-4 | |||||
| REACH Registration number: | 01-2119473793-27 | |||||
| CLP Classification: | H302+H312 Acute tox. 4
H314 Skin Corr. 1B H317 Skin Sens. 1 H330 Acute tox. 2 H335 STOT SE 3 |
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| Phenol | < 5% | CAS number: | 108-95-2 | |||
| EINECS: | 203-632-7 | |||||
| REACH Registration number: | 01-2119471329-32 | |||||
| CLP Classification: | H301 Acute tox. 3
H311 Acute tox. 3 H314 Skin Corr. 1B H331 Acute tox. 3 H341 Muta. 2 H373 STOT RE 2 |
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For the full text of the H & R phrases mentioned in this section, see section 16.
| 4 | SECTION 4: First aid measures: |
4.1 Description of first aid measures:
Always ask medical advice as soon as possible should serious or continuous disturbances occur.
| Skin contact: | remove contaminated clothing, rinse skin with plenty of water and immediately transport to hospital. |
| Eye contact: | first prolonged rinsing with water (contact lenses to be removed if this is easily done) then take to physician. |
| Ingestion: | rinse mouth, do not induce vomiting, take to hospital immediately. |
| Inhalation: | let sit upright, fresh air, rest and take to hospital. |
4.2 Most important symptoms and effects, both acute and delayed:
| Skin contact: | caustic, redness, pain, serious burns |
| Eye contact: | caustic, redness, bad looking, pain |
| Ingestion: | caustic, lack of breath, vomiting, blisters on lips and tongue, burning pain in mouth and throat, gullet and stomach |
| Inhalation: | headache, dizziness, nausea, drowsiness, unconsciousness |
4.3 Indication of any immediate medical attention and special treatment needed: none
| 5 | SECTION 5: Fire-fighting measures: |
5.1 Extinguishing media:
CO2, foam, powder, sprayed water
5.2 Special hazards arising from the substance or mixture: none
5.3 Advice for firefighters:
Extinguishing agents to be none avoided:
| 6 | SECTION 6: Accidental release measures: |
6.1 Personal precautions, protective equipment and emergency procedures:
Do not walk into or touch spilled substances and avoid inhalation of fumes, smoke, dusts and vapours by staying up windRemove any contaminated clothing and used contaminated protective equipment and dispose of it safely.
6.2 Environmental precautions:
do not allow to flow into sewers or open water.
6.3 Methods and material for containment and cleaning up:
Contain released substance, store into suitable containers. If possible remove by using absorbent material.
6.4 Reference to other sections: for further information check sections 8 & 13.
| 7 | SECTION 7: Handling and storage: |
7.1 Precautions for safe handling: handle with care to avoid spillage.
7.2 Conditions for safe storage, including any incompatibilities: keep in a sealed container in a closed, frost-free, ventilated room.
7.3 Specific end use(s):
For professional use only
| 8 | SECTION 8: Exposure controls/personal protection: |
8.1 Control parameters:
Listing of the hazardous ingredients in section 3, of which the TLV value is known
Phenol 8 mg/m³, Diethylenetriamine 4 mg/m³
8.2 Exposure controls:
| Inhalation protection: | use with sufficient exhaust ventilation. If necessary, use an air-purifying face mask in case of respiratory hazards. Use the ABEK type as protection against these troublesome levels. | ||||
| Skin protection: | handling with Viton-gloves (EN 374). Breakthrough time: >480’ Material thickness: 0,7 mm. Thoroughly check gloves before use. Take of the gloves properly without touching the outside with your bare hands. The manufacturer of the protective gloves has to be consulted about the suitability for a specific work station. Wash and dry your hands. | ||||
| Eye protection: | keep an eye-rinse bottle within reach. Tight-fitting safety goggles. Wear a face shield and protective suit in case of exceptional processing problems. | ||||
| Other protection: | impermeable clothing. The type of protective equipment depends on the concentration and amount of hazardous substances at the work station in question. | ||||
| 9 | SECTION 9: Physical and chemical properties: | ||||
9.1 Information on basic physical and chemical properties:
| Melting point/melting range: | / | |||
| Boiling point/Boiling range: | 200 °C — 272 °C | |||
| pH: | / | |||
| pH 1% diluted in water: | / | |||
| Vapour pressure/20°C,: | / | |||
| Vapour density: | not applicable | |||
| Relative density, 20°C: | / | |||
| Appearance/20°C: | liquid | |||
| Flash point: | / | |||
| Flammability (solid, gas): | not applicable | |||
| Auto-ignition temperature: | 358 °C | |||
| Upper flammability or explosive limit, (Vol %): | 13.000 % | |||
| Lower flammability or explosive limit, (Vol %): | 1.300 % | |||
| Explosive properties: | not applicable | |||
| Oxidising properties: | not applicable | |||
| Decomposition temperature: | / | |||
| Solubility in water: | not soluble | |||
| Partition coefficient: noctanol/water: | not applicable | |||
| Odour: | characteristic | |||
| Odour threshold: | not applicable | |||
| Dynamic viscosity, 20°C: | / | |||
| Kinematic viscosity, 40°C: | / | |||
| Evaporation rate (n-BuAc = 1):
9.2 Other information: |
0.300 | |||
| Volatile organic component (VOC): | 14.28 % | |||
| Volatile organic component (VOC): | / | |||
| 10 | SECTION 10: Stability and reactivity: | |||
10.1 Reactivity: stable under normal conditions.
10.2 Chemical stability: extremely high or low temperatures.
10.3 Possibility of hazardous reactions: none
10.4 Conditions to avoid: protect from sunlight and do not expose to temperatures exceeding + 50°C.
10.5 Incompatible materials:
acids, alkalines, oxidants, reductants
10.6 Hazardous decomposition products: doesn’t decompose with normal use
| 11 | SECTION 11: Toxicological information: |
11.1 Information on toxicological effects:
H302 Acute tox. 4: Harmful if swallowed.
H314 Skin Corr. 1B: Causes severe skin burns and eye damage.
H317 Skin Sens. 1: May cause an allergic skin reaction.
H331 Acute tox. 3: Toxic if inhaled.
H341 Muta. 2: Suspected of causing genetic defects.
Calculated acute toxicity, ATE oral: 1 780.174 mg/kg
Calculated acute toxicity, ATE / dermal:
| Benzyl alcohol | LD50 oral, rat: | 1,230 mg/kg | |||
| LD50 dermal, rabbit: | 1,100 mg/kg | ||||
| LC50, Inhalation, rat, 4h: | 11 mg/l | ||||
| m-phenylenebis(methylamine) | LD50 oral, rat: | 980 mg/kg | |||
| LD50 dermal, rabbit: | 3,100 mg/kg | ||||
| LC50, Inhalation, rat, 4h: | 11 mg/l | ||||
| Diethylenetriamine | LD50 oral, rat: | 500 mg/kg | |||
| LD50 dermal, rabbit: | 1,100 mg/kg | ||||
| LC50, Inhalation, rat, 4h: | 0.5 mg/l | ||||
| Phenol | LD50 oral, rat: | 340 mg/kg | |||
| LD50 dermal, rabbit: | 660 mg/kg | ||||
| LC50, Inhalation, rat, 4h: | 3 mg/l | ||||
| 12 | SECTION 12: Ecological information: | ||||
12.1 Toxicity:
| Benzyl alcohol | LC50 (Fish): | 460 mg/L (72h) | |
| EC50 (Daphnia): | 230 mg/L (48h) | ||
| NOEC (Daphnia): | 310 mg/L (72h) | ||
| EC50 (Algae): | 770 mg/L (72h) | ||
| m-phenylenebis(methylamine) | LC50 (Fish): | 87.6 mg/L (96h) | |
| EC50 (Daphnia): | 87.6 mg/L (96h) | ||
| EC50 (Algae): | 20.3 mg/L (72h) | ||
| EC50 (soil microorganisms): | > 1000 mg/L (30min) | ||
| Diethylenetriamine | LC50 (Fish): | 0,43 g/L (96h) | |
| NOEC (Daphnia): | 5,6 mg/L (21d) | ||
| EC50 (Algae): | 187 mg/L (72h) | ||
| NOEC (Algae): | 1164 mg/L (72h) | ||
| EC50 (soil microorganisms): | 32,7 mg/L (3h) | ||
| Phenol | LC50 (Fish): | 21.93 mg/L (14d) | |
| NOEC (Fish): | 4 mg/L (14d) | ||
| EC50 (Daphnia): | 3.1 mg/L (48h) | ||
| EC50 (Algae): | 61.1 mg/L (96h) | ||
12.2 Persistence and degradability:
No additional data available
12.3 Bioaccumulative potential:
No additional data available
12.4 Mobility in soil:
| Water hazard class, WGK: | 2 |
| Solubility in water: | not soluble |
12.5 Results of PBT and vPvB assessment:
No additional data available
12.6 Other adverse effects:
No additional data available
| 13 | SECTION 13: Disposal considerations: |
13.1 Waste treatment methods:
Draining into the sewers is not permitted. Removal should be carried out by licensed services. Possible restrictive regulations by local authority should always be adhered to.
| 14 | SECTION 14: Transport information: |
14.1 UN number:
2735
14.2 UN proper shipping name:
UN 2735 Amines, liquid, corrosive, n.o.s. (mixture with m-phenylenebis(methylamine); Diethylenetriamine ) , 8, II, (E)
14.3 Transport hazard class(es):
Class(es): 8
Identification number of the 80 hazard:
14.4 Packing group:
II
14.5 Environmental hazards: not dangerous to the environment
14.6 Special precautions for user:
Hazard characteristics: Risk of burns. Risk to the aquatic environment and the sewerage system.
Additional guidance:
| 15 | SECTION 15: Regulatory information: |
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Water hazard class, WGK: 2
Volatile organic component (VOC): 14.280 %
Volatile organic component (VOC): /
Composition by regulation (EC) none 648/2004:
15.2 Chemical Safety Assessment:
No data available
| 16 | SECTION 16: Other information: |
Legend to abbreviations used in the safety data sheet:
| ADR: | The European Agreement concerning the International Carriage of Dangerous Goods by Road |
| BCF: | Bioconcentration factor |
| CAS: | Chemical Abstracts Service |
| CLP: | Classification, Labelling and Packaging of chemicals |
| EINECS: | European INventory of Existing Commercial chemical Substances |
| Nr.: | number |
| PTB: | persistent, toxic, bioaccumulative |
| TLV: | Threshold Limit Value |
| vPvB: | very persistent and very bioaccumulative substances |
| WGK: | Water hazard class |
| WGK 1: | slightly hazardous for water |
| WGK 2: | hazardous for water |
| WGK 3: | extremely hazardous for water |
Legend to the R & H Phrases used in the safety data sheet:
H301 Acute tox. 3: Toxic if swallowed. H302 Acute tox. 4: Harmful if swallowed.
H302+H312 Acute tox. 4: Harmful if swallowed or in contact with skin. H311 Acute tox. 3: Toxic in contact with skin. H314 Skin Corr. 1B: Causes severe skin burns and eye damage. H317 Skin Sens. 1: May cause an allergic skin reaction. H319 Eye Irrit. 2: Causes serious eye irritation. H330 Acute tox. 2: Fatal if inhaled. H331 Acute tox. 3: Toxic if inhaled. H332 Acute tox. 4: Harmful if inhaled. H335 STOT SE 3: May cause respiratory irritation. H341 Muta. 2: Suspected of causing genetic defects. H373 STOT RE 2: May cause damage to organs through prolonged or repeated exposure. H412 Aquatic Chronic 3: Harmful to aquatic life with long lasting effects.
Reason of revision, changes of following items:
Section: 11
MSDS reference number: ECM-106407,00