Fibrescreed RC100 MTR_S.D.S

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product Identifier: FIBRESCREED RC100 MTR

Product code: HRRBRC7LV

1.2 Relevant uses of the substance or mixture and uses advised against:

Supplied for use as a professional use surface dressing for application to road surfaces.

1.3 Details of the supplier of the safety data sheet: Prismo Road Markings Limited (trading as Ennis-Flint)

5 Drumhead Road

Chorley North Industrial Park

Chorley, Lancashire

PR6 7BX

United Kingdom

Telephone Number: +44 (0) 1257 225 100

Fax Number: +44 (0) 1257 224 606

E-mail Address: info@ennisprismo.com

1.4 Emergency telephone number

+44 (0) 1257 225 100

Only available office hours Monday – Friday 0830 to 1700 (English language)

Hazards Identification

2.1 Classification of the substance or mixture

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]

Chronic Aquatic Toxicity Class 3; H412 Harmful to aquatic life with long lasting effects

2.2 Label Elements according to Regulation (EC) No 1272/2008 [CLP] Fibrescreed RC100 MTR

Pictogram: [None]

Signal word: [None]

Hazard Statements:

H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements:

P261 Avoid breathing dust.

P501 Dispose of contents/container in accordance with local/ regional/national/international regulation.

2.3 Other hazards

This mixture does not contain any substances that are assessed to be PBT or vPvB.

The product may give potential for generation of respirable dust during handling and use.

Dust may contain respirable crystalline silica. Prolonged and or high inhalation of respirable crystalline silica dust may cause lung fibrosis, commonly referred to as silicosis. Principal symptoms of lung fibrosis are cough and breathlessness. Occupational exposure to respirable dust and respirable crystalline silica should be monitored and controlled.

Composition/information on ingredients

3.1 Product Code: HRRBRC7LV 3.2 Mixtures 3.3 Hazardous components

Chemical Name

CAS-No./

EINECSNo.

Annex Index or REACH number

Pictogram(s)

H-phrase(s)

Concentrations [%]

Silica, respirable crystalline

–

Index number:

–

REACH

Registration number:

–

According to 1272/2008:

Not classified

Substance with

Workplace Exposure

Limit

According to 1272/2008:

–

≤ 50.0

Asphalt, petroleum

fumes

8052-42-4/

232-490-9

Index number:

–

REACH

Registration number:

012119480172-44

According to 1272/2008:

Not classified

Substance with

Workplace Exposure

Limit

According to 1272/2008:

–

≤ 30.0

Calcium carbonate

1317-65-3

Index number:

–

REACH

Registration number:

–

According to 1272/2008:

Not classified

Substance with

Workplace Exposure

Limit

According to 1272/2008:

–

≤ 10.0

Alkylamine derivatives

92797-22-

296-557-4

Index number:

–

REACH

Registration number:

–

According to 1272/2008:

GHS05

GHS07

GHS09

According to 1272/2008:

Acute Tox. 4

H302

Skin Corr. 1A

H314

Long-term aquatic tox. hazard 1

H410

≤ 0.30

Alkylamines

61790-33-

263-125-1

Index number:

612-286-00-X

REACH

Registration number:

According to 1272/2008:

GHS05

GHS07

According to 1272/2008:

Acute Tox. 4

H302

Asp. Tox. 1

H304

STOT RE 2 H373 (gastro- intestinal tract, liver,

≤ 0.1

GHS08

GHS09

immune system) Skin Corr. 1B

H314

Acute aquatic tox. 1 H400 (M=10)

Long-term

aquatic tox. 1

H410

(M=10)

The full hazard information for individual components if not displayed in section 2 or 3 are displayed in Section 16.

4.0. First Aid Measures

4.1 Description of first aid measures

General advice

Immediate medical attention is required if in contact with hot product. Move out of dangerous area. Show this safety data sheet to the doctor in attendance.

Inhalation

Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention immediately. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion

Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.

Get medical attention if adverse health effects persist or are severe.

Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Wash skin immediately with soap and water. Get medical attention if irritation develops and persists. If contact with hot product, cool the burn area by flushing with large amounts of water. Do not attempt to remove anything from the burn area or apply burn creams or ointments. Cover the burn area loosely with a sterile dressing, if available. Transport to the nearest medical facility for additional treatment. All burns should receive medical attention.

Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Eye contact

Cold product – Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Protect unharmed eye. Continue to rinse and get

medical attention immediately. Continue to rinse during transport. If eye irritation persists, consult a specialist.

Hot product – If contact with hot product, cool the burn area by flushing with large amounts of water. Do not attempt to remove anything from the burn area or apply burn creams or ointments. Cover the burn area loosely with a sterile dressing, if available. Transport to the nearest medical facility for additional treatment. All burns should receive medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Over-exposure signs/symptoms

Inhalation

No specific information.

Ingestion

No specific information.

Skin

Contact with hot product may cause burns.

Eyes

Contact with hot product may cause burns and severe damage to eyes. Product and dust may cause irritation to eyes.

See SECTION 11 for more detailed information on health effects and symptoms.

4.3 Indications of any immediate medical attention and special treatment needed

Notes to physician

No specific treatment. Treat symptomatically. If removal of solidified product from skin is attempted, mineral oil (not mineral spirits) or a mineral oil based ointment may be applied to help soften the product to facilitate removal.

Protection of first aid personnel

No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash Contaminated clothing thoroughly with water before removing it, or wear gloves.

5. Fire-Fighting measures

5.1 Extinguishing media Suitable

Use water spray, fog or foam, carbon dioxide. Use an extinguishing agent suitable for the surrounding fire

Not suitable

Do not use water jet.

5.2 Special hazards arising from the substance or mixture

In a fire or if heated, a pressure increase may occur. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous thermal decomposition products In combustion may emit toxic fumes.

5.3 Advice for firefighters

Special precautions for fire-fighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures 6.1 Personal precautions, protective equipment and emergency procedures

Avoid contact with skin, eyes and clothing. Hot product should be handled so that there is no risk of burns. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation.

Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8). Avoid breathing vapour or mist.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

6.3 Methods and material for containment and cleaning up Small spill :

Eliminate all ignition sources. Move containers from spill area. Dispose of via a licensed waste disposal contractor. Stop leak if without risk.

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Large spill :

Eliminate all ignition sources. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations . Contaminated absorbent material may pose the same hazard as the spilled product.

6.4 Reference to other sections

Note: see SECTION 1 for emergency contact information, SECTION 8 for personal protection and section 13 for waste disposal.

7. Handling and storage

7.1 Precaution for safe handling

Avoid contact with skin, eyes and clothing. Avoid generation and breathing of dusts. Hot product should be handled so that there is no risk of burns.

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used.

Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing dust, vapour or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use.

Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

7.3 Specific end use(s) Not applicable.

8.Exposure controls/personal protection

8.1 Control Parameters

Workplace exposure Limits as defined by UK HSE in document EH40/2005 where available:

Substance	CAS number	Workplace Exposure Limit				Comments
		Long-term exposure limit (8-hr TWA reference period)		Short-term exposure limit (15 minute reference period)		The Carc, Sen and Sk notations are not exhaustive. Notations have been applied to the substances identified in IOELV Directives
		ppm	mg.m^-3	ppm	mg.m^-3
Asphalt, petroleum fumes	8052-42-4	–	5	–	10	Asphalt, petroleum fumes
Calcium carbonate inhalable dust respirable	1317-65-3	– –	10 4	– –	– –	–
Silica, respirable crystalline		–	0.1	–	–	–

ALKYLAMINE DERIVATIVES DNELs:

Type	Route	Value	Form
Workers	Skin contact	125 µg/Kg bw/day	Long term and short term systemic effects
Workers	Inhalation	0.352 mg/m³	Long term and short term systemic effects

PNECs:

Route	Value
Fresh water	0,064 μg/l
Fresh water sediment	0,016 mg/kg dw
Soil	0,003 mg/kg dw
Sewage treatment plant	1 mg/l
Marine Sediment	0,0016 mg/kg dw
Marine water	0,0064 μg/l
Water (Intermittent release)	0,378 μg/l
Oral (Secondary Poisoning)	1 mg/kg food

8.2 Exposure controls

General

Avoid contact with skin, eyes and clothing. Hot product should be handled so that there is no risk of burns

Hygiene measures :

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure that there is sufficient ventilation of the area.

Eye and face protection

Wear tightly fitting safety goggles and Face shield that meet EN 166 a/o ANSI Z87.1 standards

Skin protection

When handling heated product wear heat resistant gloves.

Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact.

Always seek advice from glove suppliers. Select gloves approved to EU standard EN407.

Wear impermeable protective clothing, butyl rubber apron and boots.

For normal operations with hot material wear heat resistant coveralls, (with cuffs over gloves and legs over boots), and heavy-duty boots, e.g. leather for heat resistance. The use of a neck apron is recommended.

Inhalation

Provide a good standard of general ventilation. Use outdoors or ensure not less than 3 to 5 air changes per hour. In case of dust wear respiratory protective device with dust filter. Applicable standards for continuous wear time of less than 2 hour are BS EN 140 mask and BS EN 143 Filter; BS EN 1827.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Physical state: solid

Colour: black

Odour: Characteristic, bituminous Odour threshold: No data pH: Not applicable Melting Point: Approx.n/a

Initial boiling point and boiling range: No data

Flash point: >230⁰C

Evaporation rate: No data

Flammability: No data

Explosion limits

Upper: No data

Lower: No data

Vapour pressure: No data

Vapour density: No data

Relative density: 1.4 kg/l

Solubility: Insoluble in water

Partition coefficient: n-octanol/water No data

Auto-ignition temperature: No data

Decomposition temperature: No data

Viscosity: Not applicable

Explosive properties: No data

Oxidising properties: No data

9.2 Other Information

No other relevant information available

10. Stability and reactivity

10.1 Reactivity

Stable under normal conditions.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid strong bases, acids and strong oxidising agents.

10.5 Incompatible materials

Do not allow molten material to contact water or liquids as this can cause violent eruptions, splatter hot material, or ignite flammable material.

10.6 Hazardous decomposition products In combustion may emit toxic fumes.

11. Toxicological Information

11.1 Information on toxicological effects

The mixture has not been assessed for toxicological effects, the mixture classification is given in section 2 based on individual component contents. Individual component hazards are given in section 3

Toxicological information on hazardous ingredients where available: ALKYLAMINE DERIVATIVES :

Inhalation	No data available.
Skin	Corrosive Corrosive (OECD Test Guideline 404, rabbit)
Eyes	Corrosive to eyes
Ingestion	Harmful if swallowed.
Acute oral toxicity	LD50/rat: 704 mg/kg bw (Method: OECD Test Guideline 401)
Sensitisation	Not a skin sensitizer (Method : OECD Test Guideline 406 )
Germ cell mutagenicity Genotoxicity in vitro	Not genotoxic In vitro gene mutation study in bacteria: negative (Method: OECD Test Guideline 471) Tests for chromosome aberrations in vitro on mammalian cells: negative (Method: OECD Test Guideline 473) In vitro gene mutations test on mammalian cells: negative (Method: OECD Test Guideline 476)
Specific target organ toxicity :	Single exposure : No data available. Repeated exposure: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Oral: NOAEL= 15mg/kg bw/day (Method: OECD Test Guideline 422, rat)
Aspiration hazard:	No data available.

12. Ecological Information

12.1 Toxicity

Mixture classified as harmful to aquatic life with long lasting effects.

Toxicity of ingredients where available: ALKYLAMINE DERIVATIVES :

Fish:	LC50, 96 h (Oncorhynchus mykiss (rainbow trout)) : 0,168 mg/l (Method: OECD Test Guideline 203) NOEC, 96 h (Oncorhynchus mykiss (rainbow trout)) : 0,117 mg/l (Method: OECD Test Guideline 203)
Aquatic plants:	ErC50, 72 h (Pseudokirchneriella subcapitata) : 37,8 μg/l (Method: OECD Test Guideline 201) NOEC, 72 h (Pseudokirchneriella subcapitata) : 5,56 μg/l (Method: OECD Test Guideline 201)
Micro-organisms	EC50, 3 h (Activated sludge) : 75,2 mg/l (Method: OECD Test Guideline 209) NOEC, 3 h (Activated sludge) : 10 mg/l (Method: OECD Test Guideline 209)
Aquatic invertebrates:	NOEC, 21 d (Daphnia magna (Water flea)) : 3,2 μg/l (Method: OECD Test Guideline 211)

12.2 Persistence and degradability Information not available.

12.3 Bioaccumulative potential No information.

12.4 Mobility in soil No information.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be PBT or vPvB.

12.6 Other adverse effects No information.

13.Disposal considerations 13.1 Waste Treatment Methods Methods of disposal:

The generation of waste should be avoided or minimized wherever possible.

Empty containers or liners may retain some product residues.

This material and its container must be disposed of in a safe way.

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Hazardous waste:

The classification of the product may meet the criteria for a hazardous waste.

14. Transport Information

14.1 UN number: Not applicable 14.2 UN proper shipping name: Not applicable 14.3 Transport hazard: Not applicable 14.4 Packing group: Not applicable

14.5 Environmental hazards: Product is not classified as harmful to the environment.

14.6 Special precautions for user: No information available 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code

Applicable for Maritime bulk transport only. Check with carrier.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.

This substance is classified and labelled in accordance with regulation 1272/2008 and Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation

(EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

15.2 Chemical Safety Assessment

CSA not undertaken for this substance

16. Other Information

Other Hazard Information assigned to individual ingredients, but not carried to final classification:

H302: Harmful if swallowed.

H304: Harmful if swallowed.

H314: Causes severe skin burns and eye damage.

H373: May cause damage to organs through prolonged or repeated exposure.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

SDS information:

This safety data sheet is compiled using data submitted for raw materials and practical experience.

This product is intended for professional users only.

This Safety Data Sheet is prepared in compliance with regulation 1272/2008 and Regulation (EC) No

1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the

Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a

European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation

(EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

THE INFORMATION GIVEN HEREIN IS, TO THE BEST OF OUR KNOWLEDGE, CORRECT AND IS

PRESENTED IN GOOD FAITH BUT NO WARRANTY, EXPRESSED OR IMPLIED IS GIVEN.