DDi 1510 S.D.S
SAFETY DATA SHEET
DDi 1510
June 09, 2015
|
Product ID : Product Name : |
DDi 1510 DDi 1510 |
||
| Revision Date : | June 09, 2015 Date Printed : | July 10, 2015 | |
| Version:
Supplier Name : |
2.0 Supersedes Date :
SealBoss Corp. |
N.A. | |
| Address :
Emergency Phone : Information Phone : |
E. Wilshire Ave. Santa Ana, CA USA 92705
ChemTel 1-800-255-3924 OR International: +01-813-248-0585
1-714-662-4445 |
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER’S IDENTIFICATION
Fax : 1-714-662-4446
Product/Recommended Uses: For Further Information, Refer to the Product Technical Data Sheet.
Distributor Name: Dependable Depot, Inc.
Address: Lyon St. Santa Ana, CA 92705 USA
Information Phone: 1-714-541-9049
SECTION 2) HAZARDS IDENTIFICATION
Classification:
Specific Target Organ Toxicity -Single Exposure (Respiratory Tract Irritation) – Category 3
Specific Target Organ Toxicity – Repeated Exposure – Category 2
Skin Irritation – Category 2
Eye Irritation – Category 2A
Respiratory Sensitizer (Solid/Liquid) – Category 1
Skin Sensitizer – Category 1
Carcinogenicity – Category 2
Reproductive Toxicity – Category 1B
Acute aquatic toxicity – Category 1
Acute toxicity Inhalation Vapor Category 4
Pictograms:
Signal Word:
Danger
Hazardous Statements – Health:
H332 – Harmful if inhaled
H351 – Suspected of causing cancer.
H319 – Causes serious eye irritation
H360 – May damage fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H373 – May cause damage to organs through prolonged or repeated exposure.
H335 – May cause respiratory irritation
Hazardous Statements – Environmental:
H400 – Very toxic to aquatic life
Precautionary Statements – General:
P101 – If medical advice is needed, have product container or label at hand.
P102 – Keep out of reach of children.
P103 – Read label before use.
Precautionary Statements – Prevention: P273 – Avoid release to the environment.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P271 – Use only outdoors or in a well-ventilated area.
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P264 – Wash thoroughly after handling. P284 – [In case of inadequate ventilation] wear respiratory protection.
P272 – Contaminated work clothing should not be allowed out of the workplace.
P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P233 – Keep container tightly closed.
Precautionary Statements – Response:
P391 – Collect spillage.
P304 + P340 – IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 – Call a POISON CENTER/doctor if you feel unwell. P308 + P313 – IF exposed or concerned: Get medical advice/attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical advice/attention.
P342 + P311 – If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P302 + P352 – IF ON SKIN: Wash with plenty of water. P321 – Specific treatment (see section 4 on this SDS).
P332 + P313 – If skin irritation occurs: Get medical advice/attention.
P362 + P364 – Take off contaminated clothing. And wash it before reuse.
P333 + P313 – If skin irritation or a rash occurs: Get medical advice/attention.
P314 – Get Medical advice/attention if you feel unwell.
Precautionary Statements – Storage: P405 – Store locked up.
P403 + P405 – Store in a well-ventilated place. Store locked up.
Precautionary Statements – Disposal:
P501 – Dispose of contents/ container to an approved waste disposal plant.
| SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS | ||
| CAS
0068092-58-0 |
Chemical Name
POLYURETHANE PREPOLYMER |
% by Weight 20% – 37% |
| 0000084-74-2 | DIBUTYL PHTHALATE | 16% – 30% |
| 0000101-68-8 | 4,4′-METHYLENEDIPHENYL DIISOCYANATE | 15% – 27% |
| 0009016-87-9 | POLYMETHYLENE POLYPHENYL ISOCYANATE | 14% – 26% |
| 0026447-40-5 | MDI (MONOMER) | 2% – 4% |
SECTION 4) FIRST-AID MEASURES
Inhalation:
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the POISON CENTER/doctor.
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Eliminate all ignition sources if safe to do so.
Skin Contact:
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before re-use or discard. IF exposed or concerned: Get medical advice/attention.
Eye Contact:
Avoid direct contact. Wear chemical protective gloves, if necessary.
Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention. Ingestion:
Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. If vomiting occurs naturally, lie on your side, in the recovery position.
IF exposed or concerned: Get medical advice/attention.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media:
If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous.
Specific Hazards in Case of Fire:
Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can occur.
Excessive pressure or temperature may cause explosive rupture of containers.
Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.
Fire-fighting Procedures:
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions:
Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), googles, and full protective clothing are also required.
Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment:
Positive pressure, full-face piece self-contained breathing apparatus(SCBA), or positive pressure supplied air respirator with escape SCBA (NIOSH approved).
Personal Precautions:
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions:
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up:
Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the precautions on the supplier’s safety data sheets.
Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react for at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste.
Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with all relevant local, state, and federal laws and regulations regarding treatment.
SECTION 7) HANDLING AND STORAGE
General:
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Ventilation Requirements:
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to control emissions near the source.
Storage Room Requirements:
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
Do not cut, drill, grind, weld, or perform similar operations on or near containers. Do not pressurize containers to empty them. Ground all structures, transfer containers and equipment to conform to the national electrical code. Use procedures that prevent static electrical sparks. Static electricity may accumulate and create a fire hazard.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection:
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If additional protection is needed for entire face, use in combination with a face shield.
Skin Protection:
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.
Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. Wash contaminated clothing before re-wearing. Respiratory Protection:
If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value.
| Chemical Name | OSHA
TWA (ppm) |
OSHA
TWA (mg/m3) |
OSHA
STEL (ppm) |
OSHA
STEL (mg/m3) |
OSHA-
Tables- Z1,2,3 |
OSHA Carcinogen |
OSHA Skin designation | NIOSH TWA
(ppm) |
NIOSH
TWA (mg/m3) |
NIOSH
STEL (ppm) |
NIOSH
STEL (mg/m3) |
NIOSH Carcinogen |
| 4,4′-
METHYLENEDIPHEN YL DIISOCYANATE |
0.02 ceiling | 0.2 ceiling | 1 | 0.005 | 0.050 | |||||||
| DIBUTYL
PHTHALATE |
5 | 1 | 5 |
| Chemical Name | ACGIH
TWA (ppm) |
ACGIH
TWA (mg/m3) |
ACGIH STEL
(ppm) |
ACGIH
STEL (mg/m3) |
| 4,4′-
METHYLENEDIPHEN YL DIISOCYANATE |
0.005 | 0.051 | ||
| DIBUTYL
PHTHALATE |
5 |
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Density 9.38 lb/gal
Specific Gravity 1.12
VOC Regulatory 0.00 lb/gal
VOC Part A & B Combined N.A.
Appearance Amber Liquid Odor Threshold N.A.
Odor Description Mild Aromatic pH N.A.
Water Solubility Reacts with Water
Flammability N/A
Flash Point Symbol N.A. Flash Point 200 °F Viscosity N.A.
Lower Explosion Level N.A.
Upper Explosion Level N.A. Vapor Pressure N.A.
Vapor Density Heavier than air Freezing Point N.A. Melting Point N.A. Low Boiling Point 400 °F High Boiling Point N.A.
Auto Ignition Temp N.A.
Decomposition Pt N.A.
Evaporation Rate Slower than ether
Coefficient Water/Oil N.A.
SECTION 10) STABILITY AND REACTIVITY
Stability:
Material is stable at standard temperature and pressure.
Conditions to Avoid:
Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of carbon dioxide and buildup of pressure. Hazardous Reactions/Polymerization:
Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds will accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.
Incompatible Materials:
This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the reaction with water is slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal compounds. Some reactions can be violent. Material can react with strong oxidizing agents.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be formed during combustion.
SECTION 11) TOXICOLOGICAL INFORMATION
Skin Corrosion/Irritation:
Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor.
Causes skin irritation
Serious Eye Damage/Irritation:
Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause conjunctivitis. Any level of contact should not be left untreated.
Causes serious eye irritation
Carcinogenicity:
Suspected of causing cancer.
Respiratory/Skin Sensitization:
May cause allergy or asthma symptoms or breathing difficulties if inhaled
May cause an allergic skin reaction
Germ Cell Mutagenicity:
No data available
Reproductive Toxicity:
May damage fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
Specific Target Organ Toxicity – Single Exposure:
May cause respiratory irritation
Specific Target Organ Toxicity – Repeated Exposure:
May cause damage to organs through prolonged or repeated exposure.
Aspiration Hazard:
No data available
Acute Toxicity:
No data available
0000101-68-8 4,4′-METHYLENEDIPHENYL DIISOCYANATE
LC50 (rat): 369-490 mg/m3 (aerosol) (4-hour exposure) (1)
LC50 (rat): 178 mg/m3 (17.4 ppm) (duration of exposure not reported) (2)
LD50 (oral, rat): greater than 10,000 mg/kg (1,2)
LD50 (dermal, rabbit): greater than 10,000 mg/kg (1)
LD50 (oral, mouse): 2,200 mg/kg (3)
0009016-87-9 POLYMETHYLENE POLYPHENYL ISOCYANATE
LC50 (rat): 490 mg/m3 (aerosol) 4-hour exposure (22)
LD50 (oral, rat): greater than 10000 mg/kg (PMPPI) (2)
LD50 (dermal, rabbit): greater than 5 mL/kg (6200 mg/kg) (PMPPI) (2)
0000084-74-2 DIBUTYL PHTHALATE
LC50 (mouse): 17680 mg/m3 (4-hour exposure); cited as 25000 mg/m3 (2-hour exposure) (12)
LD50 (oral, rat): 8000 mg/kg (1)
LD50 (oral, mouse): 4840 mg/kg (10, unconfirmed)
SECTION 12) ECOLOGICAL INFORMATION
Toxicity:
Very toxic to aquatic life
Persistence and Degradability:
No data available.
Bioaccumulative Potential:
No data available.
Mobility in Soil:
No data available.
Other Adverse Effects:
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal:
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information:
Not regulated
IMDG Information:
Not regulated
IATA Information:
Not regulated
SECTION 15) REGULATORY INFORMATION
| CAS | Chemical Name | % By Weight | Regulation List |
| 0000084-74-2 | DIBUTYL PHTHALATE | 16% – 30% | CERCLA,HAPS,SARA312,SARA313,VHAPS,VOC,TSCA,RCRA,CA_Prop65 – California Proposition 65 |
| 0000101-68-8 | 4,4′-
METHYLENEDIPHENYL DIISOCYANATE |
15% – 27% | CERCLA,HAPS,SARA312,SARA313,VHAPS,VOC,TSCA |
| 0009016-87-9 | POLYMETHYLENE
POLYPHENYL ISOCYANATE |
14% – 26% | SARA312,SARA313,VOC,TSCA |
| 0026447-40-5 | MDI (MONOMER) | 2% – 4% | SARA312,TSCA |
| 0068092-58-0 | POLYURETHANE PREPOLYMER | 20% – 37% | SARA312,TSCA |
SECTION 16) OTHER INFORMATION
OTHER INFORMATION:
Note: As per GHS, category 1 is the greatest level of hazard within each class.
GLOSSARY:
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center
(US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC- Equivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of
Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund
Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ – Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control Act Public Law 94-469; TWA – Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials Information System.
DISCLAIMER
Limited Warranty Policy and Disclaimer for Products Supplied and/or Distributed by DDi : All recommendations, statements and technical data herein are based on tests we believe to be reliable and correct, but accuracy and completeness of said tests are not guaranteed and are not to be construed as a warranty either expressed or implied. User shall rely on his or her own information and tests to determine suitability of the product for the intended use and user assumes all risk and liability resulting from his or her use of the product. Nothing contained in any supplied materials relieves the user of the obligation to read and follow the warnings and instruction for each product as set forth in the current Technical Data Sheet, product label and Material Safety Data Sheet prior to product use. DDi warrants supplied / distributed products to be free of manufacturing defects. Seller’s and manufacturer’s sole responsibility shall be to replace that portion of the product of the manufacturer which proves to be defective. There are no other warranties by DDi of any nature whatsoever expressed or implied, including any warranty of merchantability or fitness for a particular purpose in connection with this product. DDi shall not be liable for damages of any sort, including remote or consequential damages resulting from any claimed breach of any warranty whether expressed or implied. DDi shall not be responsible for use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. In addition, no warranty or guarantee is being issued with respect to appearance, color, fading, chalking, staining, shrinkage, peeling, UV damage, excessive temperature exposure, normal wear and tear or improper application by the applicator. Damage caused by abuse, neglect and lack of proper maintenance, acts of nature and / or physical movement of the substrate or structural defect s are also excluded from the limited warranty. DDi reserves the right to conduct performance tests on any material claimed to be defective prior to any repairs by owner, general contractor, or applicator. Neither seller nor manufacturer shall be liable to the buyer or any third person for any injury, loss or damage directly or indirectly resulting from use of or inability to use the product. Recommendations and statements other than those contained in a written agreement signed by an officer of the manufacturer shall not be binding upon the manufacturer or seller. DDi reserves the right to change the properties of products without notice.
